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DRY 5: Spray Drying

DRY 5: Spray Drying
     Part 1: A Practical Guide to Selection and Design
         1. INTRODUCTION
             1.1 Background and purpose
             1.2 Scope and limitations
             1.3 Report format
         2. DESIGN GUIDE
             2.1 Preliminary examination of data
             2.2 Rough sizing on basis of air throughput
             2.3 Flowsheet considerations
             2.4 Atomisation method and chamber diameter
             2.5 Chamber selection
             2.6 Other considerations and design methods available
             2.7 Psychrometric chart calculations
             2.8 Example calculation illustrating psychrometric chart design method
                 2.8.1 Specification of requirements
                 2.8.2 Solution procedure
         3. FLOWSHEET CONSIDERATIONS
             3.1 Is the liquid to be removed water or some other material?
             3.2 Is there any volatile material present in the feed other than water or solvent that is likely to cause problems?
             3.3 Is the product or solvent toxic, carcinogenic, irritating or the like?
             3.4 Is the product a dust explosion risk?
             3.5 Does the product suffer from exposure to oxygen at drying temperature?
             3.6 Is the product sensitive to products of combustion?
             3.7 Is the product permanently damaged by heat within the exposure times applying in spray dryers?
             3.8 Can the dried product be sticky, or suffer temporary thermal damage?
             3.9 Is there a maximum temperature for final discharged product?
             3.10 Could the final product be discharged with advantage at a single point other than at the dryer itself?
             3.11 Is the spray dryer the first stage of a multi-stage drying system?
             3.12 Is product particle size classification necessary or desirable?
             3.13 Is heat available from an external source?
             3.14 What are the limits on emissions to atmosphere?
             3.15 Is heat recovery from dryer exhaust desirable?
             3.16 Can the product foam in water/solvent?
             3.17 Can the feed liquor foam?
             3.18 Are there acoustic limits to be met?
             3.19 Must special attention be paid to hygiene and cleanability?
         4. CAPACITY CONSIDERATIONS
             4.1 Agreement on required capacity
             4.2 Evaporative load variations
             4.3 Effects of transient and abnormal conditions
             4.4 Shut-down and cleaning outages
             4.5 Periodic maintenance requirements
             4.6 Maintenance of efficient operating conditions
             4.7 Effect of product properties
             4.8 Plants for multiple products
             4.9 Feedstock concentration
         5. ATOMISATION CHARACTERISTICS AND SELECTION
             5.1 Methods available
             5.2 Centrifugal atomisers
             5.3 Pressure nozzles
             5.4 Pneumatic (two-fluid) nozzles
             5.5 Maximum particle size in feedstock
             5.6 Spray-air mixing
             5.7 Cost comparison
             5.8 Product granulometry
             5.9 Erosion problems
             5.10 Use of multiple atomisers
             5.11 Design choices
             5.12 Size distribution of spray droplets
             5.13 Atomiser selection
             5.14 Re-examination of product specification
             5.15 Atomiser choice (summary)
         6. DRYING CHAMBERS
             6.1 Introduction
             6.2 Box-type dryers
             6.3 Cylindrical dryers
             6.4 Choices in chamber design parameters
             6.5 Chamber designs commonly used
             6.6 Applications of various chamber designs.
             6.7 Selection of standard size and shape
             6.8 Definition of chamber volume factor
             6.9 Effect of atomisation and air flow on chamber design
             6.10 Prevention and removal of deposits from chamber walls
             6.11 Floor sweepers for flat-bottomed chambers
             6.12 Designing for explosion risks in the dryer
             6.13 Largest median particle size for given chamber diameter
             6.14 Consideration of gas residence time in chamber sizing
         7. SELECTION OF DESIGN PARAMETERS
             7.1 Fixed design data
             7.2 Parameters which may be varied
             7.3 Detailed consideration of design variables
                 7.3.1 Flowsheet
                 7.3.2 Oxygen level
                 7.3.3 Condenser temperature
                 7.3.4 Inert gas
                 7.3.5 Partial recycle of exhaust gas without condensation
                 7.3.6 Heating means
                 7.3.7 Wet recycle of fines
                 7.3.8 Scrubber liquor
                 7.3.9 Cold air additions
                 7.3.10 Floor sweeper air
                 7.3.11 Atomisation
                 7.3.12 Dryer inlet temperature
                 7.3.13 Dryer air outlet temperature
                 7.3.14 Residence time
             7.4 Design data questionnaire
         8. NOMENCLATURE
         9. REFERENCES
         10 APPENDIX A: DERIVATION OF EQUATIONS IN SECTION 2
             10.1 Equation 2.1
             10.2 Equation 2.3
             10.3 Equation 2.7
             10.4 Equation (2.4)
             10.5 Equation 2.2
     Part 2: Atomization of Spray Dryer Feed Stocks
         1. INTRODUCTION
             1.1 Background
             1.2 Definitions
             1.3 Scope of Part
         2. TECHNOLOGICAL OPTIONS
             2.1 Introduction
             2.2 Rotary atomizers
             2.3 Pressure nozzles
             2.4 Pneumatic nozzles
             2.5 Ultrasonic nozzles
         3. APPLICATION AND SELECTION OF ATOMIZERS
         4. SPECIFICATION OF ATOMIZERS
             4.1 Introduction
             4.2 Power requirements
             4.3 Particle sizes (chamber diameter)
             4.4 Operational considerations
             4.5 Cleaning
             4.6 Scale-up
             4.7 Materials of construction
         5. COST OF ATOMIZING SYSTEMS
         6. OPERATION OF ATOMISING SYSTEMS
             6.1 Introduction
             6.2 Process control
             6.3 Safety
         7. CHARACTERISATION OF FEEDSTOCKS
             7.1 Introduction
             7.2 Feed pretreatment
             7.3 Vacuole formation
             7.4 Feed properties
         8. ATOMIZATION PHYSICS
             8.1 Introduction
             8.2 Jets
             8.3 Sheets
             8.4 Fan jets
             8.5 Dropsize distributions
         9. BEHAVIOUR OF COMMERCIAL ATOMIZERS
             9.1 Vaneless flat discs
             9.2 Vaned wheels
                 9.2.1 Introduction
                 9.2.2 Dropsizes.
                 9.2.3 Air pumping
                 9.2.4 Power requirements
             9.3 Sharp-edged discs
             9.4 Pressure nozzles
                 9.4.1 Introduction
                 9.4.2 Dropsizes
                 9.4.3 Power requirements
             9.5 Two-fluid nozzles
                 9.5.1 Introduction
                 9.5.2 Dropsizes
                 9.5.3 Power requirements
             9.6 Pneumatic-cup atomizers
             9.7 Pneumatic-bowl atomizers
         10. LESS-COMMON METHODS OF ATOMIZATION
             10.1 Introduction
             10.2 Monodisperse sprays from jets
             10.3 Ultrasonic atomization
             10.4 Atomization of supercritical fluids
         11. CONCLUSIONS AND RECOMMENDATIONS
             11.1 Overview
             11.2 Further Work
         12. REFERENCES
     Part 3: Descriptions of Programs SPRY1 and SPRY2 and Generation of Experimental Data
         1. GENERAL INTRODUCTION
         2. DESCRIPTION OF PROGRAM SPRY1
             2.1 Introduction
             2.2 Process Options
             2.3 Moisture and Energy Balances over Dryer Chamber
             2.4 Moisture and Energy Balances Over the Combustion System
             2.5 Moisture and Energy Balances with Exhaust Gas Recirculation
                 2.5.1 Indirect heating with Condenser in Circuit
                 2.5.2 Indirect Heating with no Condenser
                 2.5.3 Direct Heating with no Condenser
             2.6 Output from Moisture and Energy Balance Calculations
             2.7 The Sizing Algorithm
                 2.7.1 Wet Bulb Temperature
                 2.7.2 Drying Kinetics Model
                 2.7.3 Particle Drying Time
                 2.7.4 The Chamber Coefficient
                 2.7.5 Fitting Mode
                 2.7.6 Performance Mode
                 2.7.7 Design Mode
             2.8 Summary of Options, Modes and Restrictions
                 2.8.1 Process Options
                 2.8.2 Input Options
                 2.8.3 Operating Modes
                 2.8.4 Restrictions
             2.9 Output from Sizing Calculations
         3. DESCRIPTION OF PROGRAM SPRY2
             3.1 Introduction
             3.2 Process Options
             3.3 Moisture and Energy Balances over Dryer Chamber
             3.4 Balances over External System
             3.5 Program Output
             3.6 The Chamber Sizing Procedure
                 3.6.1 Wet Bulb Temperature
                 3.6.2 Drying Kinetics Model
                 3.6.3 Particle Drying Time
                 3.6.4 Final Stages of the Sizing Procedure
             3.7 Output from Sizing Calculations
         4. EXPERIMENTAL DATA
             4.1 General
             4.2 Particle Size (SPRY1 Program)
             4.3 Particle Size Analysis (SPRY2 Programs)
             4.4 Critical Moisture Content
             4.5 Equilibrium Moisture Content (Xe)
             4.6 The Chamber Coefficient
         5. NOMENCLATURE
         6. REFERENCES
     Part 4: User Guide to Computer Programs SPRY1 and SPRY2
     Part 5: Scientific Background
         1. PARTICLE DRYING
             1.1 Particle Size and Shape Changes during Drying
             1.2 Particle Drying Kinetics
             1.3 Equilibrium Moisture Content of the Particles
         2. PRODUCT QUALITY CONTROL
             2.1 Introduction
             2.2 Product Moisture Content
             2.3 Product Density
                 2.3.1 Higher feed solids content
                 2.3.2 More suspended solids and less dissolved solids in the feed
                 2.3.3 Deaeration of the feed
                 2.3.4 Strengthening the crust
                 2.3.5 Reducing air entrapment in the feed during atomisation
                 2.3.6 Generation of smaller droplets
                 2.3.7 Lowering the air inlet temperature
                 2.3.8 Limiting the particle temperature increase in the later stages of drying
                 2.3.9 Other methods
             2.4 Particle Charring
             2.5 Enzyme and Protein Degradation
             2.6 Loss of Secondary Volatile Components
             2.7 Other Considerations
         3. AERODYNAMICS AND PARTICLE MOTION
             3.1 Visual Observations
             3.2 Mathematical Models
         4. SIMULATION MODELS
             4.1 Historical Perspective
             4.2 The SPRY2 Approach
         5. BASIS OF MINIMUM CHAMBER DIAMETER EQUATION PRESENTED IN PART 1
         6. NOMENCLATURE
         7. REFERENCES
     Terms and Conditions of Use

If a feedstock can be pumped and atomised, a spray dryer can be used to create powders with desirable properties including size, size distribution, particle shape, form, density, colour, flowability and dispersibility. The development of scientifically based design procedures has proved to be a daunting task due to the complex nature of the various stages in the spray drying process. These include atomisation of the feed, intimate contact between the spray and hot gas, moisture evaporation from the spray, and separation and collection of the dried product from the exhaust gas. Current spray dryer designs are therefore invariably based on the results of pilot plant trials and the manufacturer's accumulated experience. It is against this background that this volume is presented. It is divided into five major self-contained parts.

Volume DRY V Part 1 A practical guide to selection and design.

This part gives a manufacturer's guide to selection and design. It includes a simple preliminary chamber sizing calculation procedure and goes on to discuss the various questions that must be addressed and answered to ensure a proper basis for consultation with vendors.


Volume DRY V Part 2 Atomisation of spray dryer feedstocks.

Part 2 is a critical review of atomisation, which is the vital process in a spray dryer, as it converts the feedstock into a spray of fine droplets. The droplet size and initial velocity and the spray angle play a major role in determining the dimensions of the drying chamber. Rotary atomisers, pressure and pneumatic nozzle options are described. The criteria for selecting and applying a particular type of atomiser are considered together with their operation and economics. The importance of feedstock rheology to atomisation is emphasised for realistic feedstocks such as thick slurries, emulsions and thixotropic pastes. Current scientific understanding of the mechanisms of atomisation is reviewed. An assessment is made of published correlations for the prediction of mean drop size. The important effect of gas entrapment on droplet formation is considered. Finally, new developments in atomisation techniques, which may find future applications in industry, are described.


Volume DRY V Part 3 Description of programs SPRY1 and SPRY2 and generation of experimental data.

In SPRY1 the spray is described by the Sauter mean diameter, whilst in SPRY2 the droplet size distribution is taken into account. These programs contain detailed flowsheeting calculations and an algorithm based on a simplified model of spray drying in which the dryer is characterised by a so-called "Chamber coefficient".


Volume DRY V Part 4 User's guide to computer programs SPRY1 and SPRY2.

This part is the comprehensive "User guide" to the computer programs.


Volume DRY V Part 5 Scientific background.

This part covers such topics as atomisation, particle drying, product quality, control, aerodynamics, particle motion and overall simulation models.